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The effect of the cobalt particle size in the ethanol steam reforming reaction at 773K for hydrogen production was investigated using cobalt on carbon nanofiber catalysts. It was found that the turnover frequency increases with decreasing Co particle size, which was attributed to the increasing fraction of edge and corner surface sites with decreasing size. Regarding catalyst stability, a decrease...
Skeletal isomerisation of n-butene to isobutene is mainly controlled by catalyst pore topology, acid strength, acid site density and location of the acid sites. It is established that the pore structure of the catalyst is the most important feature with regard to isobutene selectivity and stability. The most favourable activity versus selectivity and stability characteristics are displayed by the...
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