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The kinetics of the water–gas shift (WGS) over three newly developed chromium-free catalysts Fe 2 O 3 /ZrO 2 , Rh/ZrO 2 , and Rh/Fe 2 O 3 /ZrO 2 were investigated in a parallel six-flow reaction unit in the temperature range of 623–773K at a total pressure of 21bar. Different kinetic models based on redox and associative WGS mechanisms depending...
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