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A one-dimensional mathematical model for the corrosion of a metal surface under a porous layer (often an oxide layer) is presented using porous electrode theory. The model allows one to predict the rates of corrosion in a metallic system where oxygen reduction is the only cathodic reaction which occurs on the surfaces of both the metal and the porous oxide layer albeit at different rates. Thus the...
A one-dimensional mathematical model is presented for the free corrosion of a bare metal surface (devoid of any oxide film) under a thin electrolyte layer using mixed potential theory where anodic metal dissolution is controlled by oxygen diffusion through the electrolyte layer and by the oxygen reduction at the metal surface. A pseudo-steady state is considered wherein the oxygen diffusion is at...
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