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Zero‐dimensional nitrogen‐doped carbon dots (N‐CDs) have been proved effective when introduced into the polymerization system of aniline as the hard template to synthesis small‐sized, monodisperse and highly conductive N‐CDs/PANI (N‐CDs/PANI) nanocomposites, which were then added into acrylic (AC) resin to produce coatings with excellent corrosion resistance and antifouling performances in this paper...