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The first example of leveraging the potent, but dormant, acidity of hexafluoroantimonate by its facile hydrolysis reaction to initiate cationic curing of oxirane monomers is described. This could be applied in adhesive formulations ‘on demand’. The desirable curing reaction always coexists with the detrimental cyclic dimerisation. An in depth mechanistic study of the reaction demonstrates the conditions...
Abstract An 18-month-old girl presented with macrocytic megaloblastic anaemia followed by haemolytic uraemic syndrome. Metabolic investigations led to the identification of an inborn error of cobalamin metabolism consisting of defective methylcobalamin biosynthesis, probably cobalamin G, since methionine synthase activity was decreased under standard reducing conditions. Despite treatment, pulmonary...
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