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Summary.The first optically active taurine conjugate of a bilirubin was prepared by reaction of taurine sodium salt with the mixed anhydride formed from reaction of (S,S)-dimethylmesobilirubin-XIII with isobutyl chloroformate. Analysis of the circular dichroism spectra of the conjugate in water and chloroform indicate a conformational preference for the (M)-helical ridge-tile conformation, thus providing...
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