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Nonprotein amino acids are being extensively used in the design of synthetic peptides to create new structure mimics. In this study we report the effect of methylene group insertions in a heptapeptide Boc‐Ala1‐Leu2‐Aib3‐Xxx4‐Ala5‐Leu6‐Aib7‐OMe which nicely folds into a mixed 310‐/α‐helical structure when Xxx= Ala. Analogs of this peptide have been made and studied by replacing central Xxx4 residue...
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