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The LiLa(MoO4)2:Sm3+ and LiLa(MoO4)2:Sm3+,Bi3+ phosphors were prepared using the citric‐acid‐fueled combustion method and the influence of concentrations of Bi3+ dopant on LiLa(MoO4)2:Sm3+ red luminescence was investigated. The LiLa(MoO4)2:Sm3+ and LiLa(MoO4)2:Sm3+,Bi3+ samples matched well with the scheelite structure and I41/a space group and did not detect structural changes. Under an excitation...