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The surface structure of fluoroapatite (0001) (FAp0001) under quasi‐dry and humid conditions has been probed with surface X‐ray diffraction (SXRD). Lateral and perpendicular atomic relaxations corresponding to the FAp0001 termination before and after H2O exposure and the location of the adsorbed water molecules have been determined from experimental analysis of the crystal truncation rod (CTR) intensities...