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Wir berichten über die Synthesen, Kristallstrukturen und physikalischen Eigenschaften von [HFe19O14(OEt)30] und [{Fe11(OEt)24}∞]. Das oktaederförmige Molekül [HFe19O14(OEt)30] kann als dreidimensionaler Ausschnitt aus dem Natriumchloridgitter aufgefasst werden, wobei das zentrale Eisenion von sechs μ6‐Oxo‐Gruppen koordiniert ist. [{Fe11(OEt)24}∞] ist ein gemischtvalentes Koordinationspolymer, in dem...
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