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Both the intrinsic and extrinsic contributions to the high energy storage properties of (K0.5Na0.5)NbO3 were investigated herein by employing Bi(Mg2/3Ta1/3)O3 as a second component to synthesize novel environment‐friendly energy storage ceramics. The role of the second component was confirmed to reduce the intrinsic activation of electrons, which effectively improves the band gap values and reduces...
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