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Mn nanoclusters have been prepared on a Si(111)-7x7 surface by substrate-induced spontaneous clustering due to delicate control of growth kinetics. An ex situ soft X-ray absorption spectroscopy (XAS) using synchrotron radiation has been used to clarify electronic structures of the nanoclusters. The small value of XAS L 3 -L 2 branching ratio and spectrum line-shape for the Mn clusters...
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