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The uncondensed form of polymeric carbon nitrides (PCN), generally known as melon, is a stacked 2D structure of poly(aminoimino)heptazine. Melon is used as a photocatalyst in solar energy conversion applications, but suffers from poor photoconversion efficiency due to weak optical absorption in the visible spectrum, high activation energy, and inefficient separation of photoexcited charge carriers...
The three transition metal complexes of the ligand named as 2,4‐dibromo‐6‐{[2‐(1,1‐dioxo‐1H‐benzoisothiazole‐3‐yl‐amino)‐ethylimino]‐methyl}‐phenol 3 were synthesized with divalent manganese, cobalt and nickel metal ions and characterized by employing different analytical methods including UV–visible, FT‐IR and elemental analyses. The crystal structures of Mn (II) complex 4, Co (II) complex 5, and...