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The synthesis of fluorinated C-mannopeptides and their evaluation as E- and P-selectin inhibitors is described. These molecules are difluorinated analogues of CH 2 -glycopeptides already reported to act as sLe x mimics. The α and β anomers of these CF 2 -glycopeptides have been prepared, as well as their 1-hydroxy analogues which were present in solution as an equilibrium mixture...
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