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XP spectra of a Cu(110) surface exposed to methyl mercaptan at 290 K show the presence of an adsorbate assigned to mercaptide, CH 3 S(a). Scanning tunneling microscopic (STM) images show that the formation of the adsorbed mercaptide (CH 3 S(a)) is accompanied by a restructuring of the surface. The reconstructed surface is characterized by very narrow terraces (typically 10-15 Å wide)...