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Ca0.6(Li0.5Bi0.5‐xPrx)0.4Bi2Nb2O9 ceramics were prepared via a solid‐state reaction method. The effect of the Pr content on the structural and electrical properties was systematically investigated. X‐ray diffraction (XRD) combined with Rietveld refinement and X‐ray photoelectron spectroscopy (XPS) demonstrated that a moderate amount of Pr3+ can be incorporated into the NbO6 octahedra, while excess...
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