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Solvothermal reaction of 3-aminoisonicotinic acid (Haina) and Cu(NO3)2·2.5H2O gave a novel two-dimensional (2D) microporous metal–organic framework, [Cu(aina)2(DMF)]·DMF (1, DMF=N,N-dimethylformamide). Single-crystal X-ray crystallographic study of compound 1 revealed that Cu(II) ions are linked by aina− ligands forming square grid-like layers, which stack together via multiple hydrogen bonding interactions...
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