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Here, we present a new class of terpyridine complexes of the transition‐metal ions, iron(II), ruthenium(II), and osmium(II), overcoming the poor emission properties typical for this class of polypyridyl complexes. These complexes show, besides an increased room‐temperature emission quantum yield and a prolonged lifetime of the metal‐to‐ligand charge‐transfer (MLCT) states, dual emission from two well‐separated...
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