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The hexanuclear methoxo-oxovanadium cluster V 6 O 7 (OCH 3 ) 12 (1) is investigated by electrospray ionization in methanol solution. Collision experiments unravel the fragmentation schemes of the molecular ions 1 + and 1 - as well as the H + , Na + , and Cs + adducts of 1. In general, fragmentation of the hexanuclear cluster...
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