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The reduction of nitric oxide by carbon monoxide on the (100) surface of platinum is studied using synchrotron X-ray photoelectron spectroscopy. It is found that NO dissociates more readily than previously thought and dissociation is found to yield different oxygen species. The removal of one of these dissociation products is suggested to be the rate determining step of the NO-CO reaction under the...
The interaction of nitric oxide (NO) with the clean, reconstructed (100) surface of platinum is studied using synchrotron X-ray photoelectron spectroscopy. It is found that molecular adsorption at 200 K yields two different molecular NO species. Above 250 K, NO is found to adsorb both dissociatively and molecularly, giving rise to an oxygen/NO coadsorption structure with a molecular coverage that...
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