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Two alkali metal phenolate/phenol complexes are reported. The cations are pseudo-octahedrally coordinated by oxygen atoms and the π-systems of phenolates and solvent phenols. The ratio of phenolate/phenol determines whether the oxygen atom of the phenolate participates in the coordination of the metal. In cesium phenolate·2 phenol, both phenolate and phenol solvent coordinate the metal via oxygen...
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