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Homocoupling of arylboronic acids was successfully carried out by Pd/C in water/2-propanol (9:1 volume ratio) under air to obtain symmetric biaryls in good yield. The base-free, ligand-free system and the heterogeneous nature of the catalysts allow for a practical and environmentally friendly operation. The influence of the co-solvent ratio and the reaction temperature was studied. The catalyst showed...
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