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In this paper, we report the syntheses, crystal structures, and magnetic properties of two manganese(II)–octacyanoniobate(IV)-based magnets: Mn II2 [Nb IV (CN) 8 ](3-pyridinemethanol) 8 ·2H 2 O (1) and Mn II2 [Nb IV (CN) 8 ](3-aminopyridine) 8 ·2H 2 O (2). 1 and 2 possess 3D network structures where a [Nb(CN)...
Cu 3 [W(CN) 8 ] 2 (pyrimidine) 2 (3-cyanopyridine) 2 ·4H 2 O, a cyanide-bridged copper(II) octacyanotungstate(V) with two types of organic ligands (pyrimidine and 3-cyanopyridine), is prepared. In this compound, the coordination geometry of W is an 8-coordinated bicapped trigonal prism where five CN groups of [W(CN) 8 ] are bridged to five Cu...
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