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Using high-resolution scanning tunneling microscopy (STM) we have studied the oxidation of ultrathin FeO films grown on Pt(111). At the initial stage of the FeO film oxidation by atomic oxygen exposure, we identified three distinct types of line defects, all of which form boundaries between FeO domains of opposite orientation. Two types of line defects appearing bright (type-i) and dark (type-ii)...
Using scanning tunneling microscopy (STM), X-ray photoemission spectroscopy (XPS) and density functional theory (DFT) calculations we have studied the reduction of ultra-thin films of FeO(111) grown on Pt(111) after exposure to atomic hydrogen at room temperature. A number of new ordered, partly-reduced FeO x structures are identified and as a general trend we reveal that all the reduced FeO...
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