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Pore space partition (PSP) is an effective materials design method for developing high‐performance small‐pore materials for storage and separation of gas molecules. The continued success of PSP depends on broad availability and judicious choice of pore‐partition ligands and better understanding of each structural module on stability and sorption properties. Here, by using substructural bioisosteric...
A new perspective is proposed in the design of pore‐space‐partitioned MOFs that is focused on ligand symmetry properties sub‐divided here into three hierarchical levels: 1) overall ligand, 2) ligand substructure such as backbone or core, and 3) the substituent groups. Different combinations of the above symmetry properties exist. Given the close correlation between nature of chemical moiety and its...
Metal trimers [M3(O/OH)](OOCR)6 are among the most important structural building blocks. From these trimers, a great success has been achieved in the design of 6‐ or 9‐connected framework materials with various topological features and outstanding gas‐sorption properties. In comparison, 8‐connected trimer‐based metal–organic frameworks (MOFs) are rare. Given multiple competitive pathways for the formation...
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