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A Grand Canonical Monte Carlo study has been performed in order to compare the different CO2 adsorption mechanisms between two members of the MIL-n family of hybrid metal-organic framework materials. The MIL-53 (Al) and MIL-47 (V) systems were considered. The results obtained confirm that there is a structural interchange between a large pore and narrow pore forms of MIL-53 (Al), not seen with the...
Abstract Molecular models of disaccharides, and single and double helices up to eight monomers in length have been constructed of the two types of glycosidic linkage in the carrageenan chain. These links are a galactose to anhydrogalactose link (GA link), and an anhydrogalactose to galactose link (AG link). These models are also based on -carrageenan, which contains a 4-sulphate galactose ring. The...
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