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The preparation, photophysics, and solid-state structures of three osmium cored complexes are reported. The osmium complexes take the general form of [OsCl(N–N)(L–L)(CO)] + hexafluorophosphate where N stands for a derivative of 1,10-phenanthroline and L stands for a phosphine type ligand. The emission of the complexes is shown to be blue shifted to the osmium emission of Os(bpy) 3 ...
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