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Picosecond to microsecond time-resolved infrared spectroscopy (TRIR) has been used to investigate the photochemistry of [CpFe(CO) 2 ] 2 . The early-time TRIR spectra are dominated by vibrationally hot transient species and this leads to spectra with broad featureless bands. The majority (84%) of the well characterized Cp 2 Fe 2 (μ-CO) 3 , with a band at 1824cm...
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