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A series of 5,10,15‐tris(pentafluorophenyl) doubly N‐confused bilanes were synthesized in a stepwise manner with the aid of sterically demanding N‐protecting groups, in which the difference in reactivity between regular pyrrole and N‐confused pyrrole plays a crucial role in the synthetic strategy. Some doubly N‐confused bilanes were converted into porphyrinoids or a unique 2:2 copper(II) complex with...
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