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Two isostructural square grid networks were formed by reacting a Langmuir monolayer of an amphiphilic pentacyanoferrate (3+) complex with aqueous Co 2+ or Mn 2+ ions dissolved in the subphase. Confinement of the reactants to the air-water interface discriminates against the formation of higher dimensional products and directs the lateral propagation of a polymeric two-dimensional...
Metal octadecylphosphonate Langmuir-Blodgett (LB) films of a series of divalent and trivalent metals have been prepared and characterized. The films are each shown to be LB analogs of known solid-state metal organophosphonates possessing a two-dimensional ionic-covalent metal phosphonate network. The metal phosphonate lattice crystallizes during the LB deposition process. LB films of octadecylphosphonic...
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