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Stoichiometric and catalytic reactions of Ru(II) phosphine complexes with alkynes, olefins, and enynes are described. The hydride complex RuCl(CO)H(PPh 3 ) 3 (1) reacts with the double bond of a cis-enyne whereas it reacts with triple bonds oftrans -enynes. Metathesis of vinyl silanes with olefins are catalyzed by 1 where β-Si elimination is the key step. Dimerizations of t ...
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