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We report the formation of an ionomeric network in a poly(l,d-lactide) hybrid nanocomposite, (PLDLA-HYB) during in-situ melt polymerization of l,d-lactide in the presence of magnesium/aluminum layered-double-hydroxide (LDH) without added catalyst.The effect of LDH mass loading and reaction time on molecular mass and yield of soluble poly(l,d-lactide) (PLDLA-SOL) present in the hybrid was investigated...
A polyhedral oligomeric silsesquioxane (POSS) tethered imidazolium surfactant was used to exchange montmorillonite for the preparation of polymer nanocomposites in polystyrene, poly(ethylene-co-vinyl acetate), and polyamide-6 using a melt blending technique. Simultaneous temperature resolved small angle X-ray scattering and wide angle X-ray diffraction was used to monitor the surfactant stability...
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