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The syntheses and characterization of a series of zinc complexes containing the tripodal ligand bis(5-tert-butyl-3-methylpyrazol-2-yl)acetic acid (H2) which is designed to model the 2-His-1-carboxylate facial triad observed in the active sites of various metalloenzymes such as carboxypeptidase A (CPA) and thermolysin (TLN) are reported. Pseudotetrahedral complexes isolated include [Zn2(CH 3 ...
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