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Einzelmolekülmagnete. K. Katoh, M. Yamashita et al. nutzen in ihrer Zuschrift auf S. 9406 Tb3+‐Ionen, um die Spindynamik über die Ausrichtung von Einzelmolekülmagneten (SMMs) im Kristall zu verbessern.
Magnetic dipole interactions are dominate in quasi one‐dimensional (1D) molecular magnetic materials, in which TbNcPc units (Tb3+=terbium(III) ion, Nc2−=naphthalocyaninato, Pc2−=phthalocyaninato) adopt a structure similar to TbPc2 single‐molecule magnets (SMMs). The magnetic properties of the [TbNcPc]0/+ (neutral 1 and cationic 2) with 1D structures are significantly different from those of a magnetically...
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