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The iron complexes with the phenoxyalkanoic acids 3,4-D, 2,3-D and 2,4,5-T in the presence or not of a nitrogen donor heterocyclic ligand, phen, were prepared and characterized. Interaction of Fe(III) with phenoxyalkanoic acids and phen leads to dinuclear neutral complexes while the absence of phen favours trinuclear cationic or tetranuclear neutral forms. The crystal structure of hexakis(2,3-dichlorophenoxyacetato)tris(methanol)oxotri-iron(III)...
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