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This paper describes the synthesis of the Zn(II) complex with H2L=2-hydroxyiminopropanoic acid. The final structure incorporated two linear dimeric anions with two Zn2+ atoms, which are linked by a carbonate anion into a tetranuclear unit. In each dinuclear unit, the two Zn(II) ions are coordinated by three molecules of the doubly deprotonated ligand in two different coordination modes. This result...
By using a synthetic approach alternative to the ones described up to now two tri- and tetranuclear mixed valence Co(II,III) complexes have been obtained ([Li(H 2 O) 4 ] 2 [Co(CoL 3 ) 2 (Li(H 2 O) 3 ) 2 ] and K[Co(CoL 3 ) 2 Co(H 2 O) 5 ]·H 2 O, respectively) in which the cobalt ions are linked by...
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