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Square‐planar d8‐ML4 complexes might display subtle but noticeable local Lewis acidic sites in axial direction in the valence shell of the metal atom. These sites of local charge depletion provide the electronic prerequisites to establish weakly attractive 3c–2e M⋅⋅⋅HC agostic interactions, in contrast to earlier assumptions. Furthermore, we show that the use of the sign of the 1H NMR shifts as major...
Experimentelle Ladungsdichteanalysen zeigen signifikante Unterschiede in der Natur β‐agostischer Bindungen in den Komplexen früher und später Übergangsmetalle M. Im Fall der späten M‐Alkyle mit dn‐Konfiguration kann die β‐agostische Wechselwirkung mit einem modifizierten Dewar‐Chatt‐Duncanson‐Modell beschrieben werden, das drei σ/π‐Bindungskomponenten umfasst, wohingegen ein delokalisiertes Orbital...
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