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Interaction of rat and human cystathionine-β-synthase (CBS) with various potential ligands has been studied by visible and EPR spectroscopy in order to explore the coordination chemistry of this atypical hemeprotein. Ferric CBS did not react with any classical hemeprotein ligands, such as various imidazole and pyridine derivatives, N −3 and isonitriles RNC. Ferrous CBS also failed to...
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