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This review focuses on synthesis, structure and binding properties of crown compounds and their open-chain analogues containing a trithiadiazapentalene building block. This heterocyclic unit favours in particular the complexation and solvent extraction of the soft transition metal ions Ag(I), Pd(II), Hg(II) and Au(III). The redox active system trithiadiazapentalene/trithiotriuret introduced into a...
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