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Two phenol-based unsymmetrical dinucleating macro-acyclic ligands (LH 2 ), which can contiguously accommodate two metal ions, one in a hexa-coordinate (N 4 O 2 ) site and the other in a tetra-coordinate (N 2 O 2 ) site, and their heterodinuclear complexes [ZnLM II ] 2+ , where M=Cu or Ni, were prepared using a stepwise method. One of the ligand...
Novel heterodinuclear complexes type [Zn II LM II ](ClO 4 ) 2 where L is a phenol-based ligand with two contiguous hexa-(N 4 O 2 ) and tetra-coordination (O 2 N 2 ) sites and M=Cu or Ni were prepared by a stepwise procedure. The prepared mono- and dinuclear complexes were characterized by elemental analysis, molar conductance measurements,...
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