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A series of new mononuclear and carboranylcarboxylate‐bridged dinuclear copper(II) compounds containing the 1‐CH3‐2‐CO2H‐1,2‐closo‐C2B10H10 carborane ligand (LH) has been synthesized. Reaction of different copper salts with LH at room temperature leads to dinuclear compounds of the general formula [Cu2(μ‐L)4(Lt)2] (Lt=thf (1), Lt=H2O (1′)). The reaction of 1 and 1′ with different terminal pyridyl...
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