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The newly synthesized phosphorus‐ and arsenic‐containing analogues of the thio‐ and seleno‐cyanate anions, PCSe−, AsCS−, and AsCSe−, as well as the known ion NCSe− were investigated in the gas phase by negative‐ion photoelectron spectroscopy (NIPES), velocity‐map imaging (VMI) spectroscopy, and quantum‐chemical computations. The electron affinities (EA), spin–orbit (SO) splittings, and “symmetric”/“asymmetric”...
Cyanat‐Homologe Vier schwere CN−‐Homologe wurden von J. M. Goicoechea, B. Chen, X.‐B. Wang et al. mittels Negativionen‐Photoelektronenspektroskopie, Photoelektronenbildgebung und quantenchemischen Berechnungen in ihrem Forschungsartikel auf S. 15206 untersucht.
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