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Quantum yields for the photo-substitution of Cr(CO) 4 phen (phen = 1,10-phenanthroline) by PMe 3 and PPh 3 (L) to produce Cr(CO) 3 (L)phen were determined as a function of nucleophile concentration, irradiation wavelength and pressure. The results show that LF photolysis is decelerated significantly on increasing pressure, which is in line with a limiting dissociative...
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