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The synthesis of a new bidentate ligand, 1-(2-methoxyphenyl)-2,3,4,5-tetramethyl-cyclopentadiene (1), as well as its corresponding constrained geometry titanium complex, 2-tetramethylcyclopentadienyl-phenoxytitanium dichloride [(TCP)TiCl 2 , 2], was described. Complex 2 was synthesized by reaction of TiCl 4 with the lithium salt of 1, followed by CH 3 Cl elimination at 65°C...
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