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The structures and photophysical properties of Ln(III) [europium(III), terbium(III) and gadolinium(III)] complexes with the Schiff base ligands L: (E)-N′-((2-hydroxynaphthalen-1-yl)methylene)acetohydrazide have been investigated. Single crystal X-ray structure of the Eu(III) complex shows two unsymmetrical metal centers that are directly linked by three, near symmetrical phenoxo bridges. The complex...
Crystallisation of simple cyanoruthenate complex anions [Ru(NN)(CN) 4 ] 2− (NN=2,2′-bipyridine or 1,10-phenanthroline) in the presence of Lewis-acidic cations such as Ln(III) or guanidinium cations results, in addition to the expected [Ru(NN)(CN) 4 ] 2− salts, in the formation of small amounts of salts of the dinuclear species [Ru 2 (NN) 2 (CN) 7...
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