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Treatment of an unsymmetrical bis(imino)pyridyl-thiolate zinc(II) complex [Zn II (LN 3 S)(OTf)] (1) with LiAlH 4 results in the double reduction of the two imino groups in the ligand backbone, and at the same time causes a rare transmetalation reaction to occur. The products formed in this reaction are two novel aluminium(III) bis(amido)pyridyl-thiolate complexes [(R,S/S,R-[Al...
Two related heteroscorpionate N 2 S(thiolate) ligands L 1 and L 2 have been employed in the synthesis of new zinc(II) and iron(II) complexes. These ligands contain two imidazolyl donors and one alkylthiolate donor connected by a central carbon atom. The ligand L 1 was reacted with ZnBr 2 to give the trinuclear zinc complex [(L 1 ) 3 Zn 3...
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