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The effect of the polymer dimension and the nature of the end-group of oligomer models containing pentacence ([pen]) and BODIPY ([BOD]) alternating with the organometallic fragment trans-bis(trialkylphosphine)platinum(II) ([Pt]), i.e. ([Ar]n–[Pt]m)x with [Ar] = C≡C–[pen]–C≡C, C≡C–[BOD]–C≡C, and 1 < x < 4, on their structures and optical properties were investigated by means of DFT and TDDFT...
A polymer ([Pt]–ZnP)n (ZnP = bis-meso-(hexahexyltruxene)zinc(II) porphyrin; [Pt] = trans-bis(phenylacetylene)bis(tributylphosphine)platinum(II)) was prepared from bis-meso-(hexahexyltruxene)zinc(II) porphyrin and trans-dichlorobis(tributylphosphine)platinum(II) and exhibits fluorescence and phosphorescence from truxene (Tru) and ZnP, and phosphorescence from [Pt] all at once. Evidence for singlet...
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