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This review is focused on carbonfluorine bond activation taking place at platinum group metal – PGM=Ru, Os, Rh, Ir, Pd and Pt – coordination compounds. It will specifically address the relevant examples in the area of fluorocarbon coordination to PGM leading to, at least, one CF bond cleavage by surveying the work reported since 1994, covering the literature up to August 2004.
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