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Inorganic random networks composed of silicon, boron, nitrogen, and carbon constitute a novel class of ceramics with outstanding durability at elevated temperatures. The only approach known to their synthesis is the pyrolysis of appropriate pre-ceramic polymers, which on their part are either accessible via co-condensation of different molecular species, or by polycondensation of single source precursors...
A brief review of polymer routes for the production of ceramics is given. The main emphasis is laid on systems derived from the single source precursor Cl 3 Si(NH)BCl 2 . This precursor has been developed in order to meet the objective of synthesizing amorphous multinary nitridic or carbidic ceramics. The synthesis of the single source precursor, its polymerization and finally pyrolysis...
A brief review of polymer routes for the production of ceramics is given. The main emphasis is laid on systems derived from the single source precursor Cl 3 Si(NH)BCl 2 . This precursor has been developed in order to meet the objective of synthesizing amorphous multinary nitridic or carbidic ceramics. The synthesis of the single source precursor, its polymerization and finally pyrolysis...
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