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Three new Cd(II) complexes containing 3-bpdb ligands with amide moiety as hydrogen-bond capable backbone, formulated as [Cd(3-bpdb)X 2 ] n (3-bpdb=N,N′-dipyridin-3-ylpyridine-2,6-dicarboxamide, X=Cl (1), Br (2), and I (3)), have been synthesized. All three compounds show 1-dimensional looped chain structures, and intra- and inter-molecular hydrogen bonding interactions provide 2-dimensional...
Six new structures of Cd(II) complexes containing Hdpa ligands have been determined. With chloride and bromide, Cd(II) ions produce halide-bridged dinuclear units 1 and 2 while CdI 2 produces mononuclear unit 3 without halide-bridging. Cd(II) ions produce mono-Hdpa complex 4 with chelating benzoate, di-Hdpa complex 5 with coordinating NO3- anion, and tri-Hdpa complexes 6 and 7 with non-coordinating...
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